Sapphire is a superior window material in many ways. Because of its extreme surface hardness, sapphire can be scratched by only a few substances (such as diamond or boron nitride) other than itself. Chemically inert and insoluble in almost everything except at highly elevated temperatures, sapphire can be cleaned with impunity. For example, even hydrogen fluoride fails to attack sapphire at temperatures below 300°C. Sapphire exhibits high internal transmittance all the way from 150nm (vacuum ultraviolet) to 6000nm (middle infrared).

Because of its great strength, windows made from sapphire can be much thinner than windows of other glass types, and therefore are useful even at wavelengths that are very close to their transmission limits. Because of the exceptionally high thermal conductivity of sapphire, thin windows can be very effectively cooled by forced air or other methods. Conversely, sapphire windows can easily be heated to prevent condensation.

Sapphire is single-crystal aluminum oxide (Al₂O₃). Because of its hexagonal crystalline structure, sapphire exhibits anisotropy in many optical and physical properties. The exact characteristics of an optical component made from sapphire depend on the orientation of the optic axis or c-axis relative to the element surface. Sapphire exhibits birefringence, a difference in index of refraction in orthogonal directions. The difference in index is 0.008 between light traveling along the optic axis and light traveling perpendicular to it.

The transmission of sapphire is limited primarily by losses caused by surface reflections. The high index of sapphire makes magnesium fluoride almost an ideal single-layer antireflection coating. When a single layer of magnesium fluoride is deposited on sapphire and optimized for 550nm, total transmission of a sapphire component can be kept above 98% throughout the entire visible spectrum.

The external transmittance of sapphire is shown in the figure below: